Abstract

Abstract The structures of the five-coordinate compounds RuCl2(CO) (PCY3)2 and OsHCl(CO) (PCy3)2 are discussed and the electronic spectra of these types of compounds reported. The preparation and properties of the complexes MHCl(CO)(PCy3)2L where L=acetylene or phenylacetylene. M=Ru or Os and PCy3=tricyclohexylphosphine are described.

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