Abstract
Ruthenium(ii) complexes with chelating N-heterocyclic carbene (NHC) ligands were studied in the arylation of phenyl group in 2-phenylpyridine and 1-phenylpyrazole with aryl chlorides in water. Complexes with NHC-ligands containing a hemilabile coordinating N-carboxylatomethyl group enable fast and selective ortho-CH-diarylation in the absence of carboxylate-assisting additives.
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