Abstract
A novel 4,5- seco-caryophyllane sesquiterpenoid derivative, rumphellaone A ( 1), which was found to possess an unprecedented γ-lactone moiety, was isolated from the gorgonian coral Rumphella antipathies. The structure of 1 was elucidated by spectroscopic method. A plausible biosynthetic pathway of compound 1 was proposed.
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