Abstract
The aerobic oxidation of benzylic alcohols to their corresponding aldehydes was performed in a RuCl3 · 3H2O–dicyclohexylamine (DCHA) catalyst system under ambient atmosphere at room temperature. It is noteworthy that the RuCl3 · 3H2O–DCHA system displayed a preference for the primary versus secondary benzylic alcohols in both intermolecular and intramolecular competition experiments.
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