Rubber-Styrene Block Copolymers in Adhesives

Abstract

Abstract Rubber-styrene block copolymers are materials such as the A-B-A type block copolymers, where A represents a block of polystyrene and B represents a rubber block, usually polybutadiene, polyisoprene or an olefin rubber. Because polymers of this type form a physically crosslinked network structure, the polymers are thermoplastic as well as being strong and rubbery. Because of their unique structure, block copolymers are well suited for use in a wide variety of adhesives. Block copolymers can be formulated with resins, plasticizers, and fillers to meet performance requirements ranging from those of a soft, tacky pressure-sensitive adhesive to those of a stiff, high strength construction or assembly adhesive. Adhesives based on the block copolymers can be mixed and applied, either in solvent or as hot melts, using standard processing equipment. Research is continuing on block copolymer technology, formulating technology, and processing technology which should further expand the applications of block copolymers in adhesives.