Abstract

We report the first synthesis of Ru(II) tris(3,8‐dibromo‐1,10‐phenanthroline) bishexafluorophosphate (1), and we demonstrate its utility as a building core for the divergent synthesis of hyperbranched systems by coupling with phenylacetylene in the preparation of Ru(II) tris(3,8‐diphenylethynyl‐1,10‐phenanthroline) dihexafluorophosphate (2).

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