Abstract
The high-resolution infrared spectrum of DCF3 was investigated in the 2000cm−1 region, with the aim of assigning and analyzing the overtone bands 2ν5 (A1+E), as well as the combination band ν2+ν5 (E). The present paper reports on the first high-resolution study of the v2=v5=1 and v5=2 levels, through the analysis of the combination ν2+ν5 and the overtone 2ν5∓2 bands respectively. This analysis can be thought of as a necessary step toward the reinvestigation of the complicated vibrational pattern in the CD stretching fundamental region.
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