Abstract
β-stabilized Ti-alloys present several unexplored and intriguing surprises in relation to orthorhombic α″ phases. Among them are (i) the diffusion-controlled formation of transitional α″iso, α″lean and α″rich phases and ii) the highly anisotropic thermal expansion of martensitic α″. Using the prototypical Ti-Nb system, we demonstrate that the thermodynamic energy landscape reveals formation pathways for the diffusional forms of α″ and may lead to a stable β-phase miscibility gap. In this way, we derive temperature-composition criteria for the occurrence of α″iso and resolve reaction sequences during thermal cycling. Moreover, we show that the thermal expansion anisotropy of martensitic α″ gives rise to directions of zero thermal strain depending on Nb content. Utilizing this knowledge, we propose processing routes to achieve null linear expansion in α″ containing Ti-alloys. These concepts are expected to be transferable to other Ti-alloys and offer new avenues for their tailoring and technological exploitation.
Highlights
Matthias Bönisch 1,3*, Mihai Stoica2 & Mariana Calin[1] β-stabilized Ti-alloys present several unexplored and intriguing surprises in relation to orthorhombic α′′ phases
Using the prototypical Ti-Nb system, we demonstrate that the thermodynamic energy landscape reveals formation pathways for the diffusional forms of α′′ and may lead to a stable β-phase miscibility gap
Our calculations demonstrated that the question about the existence of a stable β miscibility gap in Ti-Nb is not answered consistently by the current models and should receive special attention in future modelling efforts
Summary
Matthias Bönisch 1,3*, Mihai Stoica2 & Mariana Calin[1] β-stabilized Ti-alloys present several unexplored and intriguing surprises in relation to orthorhombic α′′ phases. Among them are (i) the diffusion-controlled formation of transitional α′′iso, α′′lean and α′′rich phases and ii) the highly anisotropic thermal expansion of martensitic α′′. Using the prototypical Ti-Nb system, we demonstrate that the thermodynamic energy landscape reveals formation pathways for the diffusional forms of α′′ and may lead to a stable β-phase miscibility gap.
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