Abstract

A [3]rotaxane consisting of a bis( sec-ammonium)-type axle and two functionalized dibenzo-24-crown-8-ether wheels was prepared in a good yield. The two point connection of the wheel components placed on the axle of the rotaxane was achieved by the Michael addition of hexanedithiol to the methacrylate C C bonds of the wheels to afford the corresponding [2]rotaxanes.

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