Abstract
Rotationally resolved photoelectron spectra are reported for rovibronically state-selected autoionizing levels of water. These photoelectron spectra are helpful for the spectroscopic assignment of the autoionizing levels and provide considerable dynamical information on the mechanisms for the transfer of energy and angular momentum between the ion core and the Rydberg electron. As a result of angular momentum restrictions, photoelectron spectra for J=0 autoionizing levels provide a direct partial wave analysis for the ejected photoelectrons.
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