Abstract
The ground state rotational spectra of HCP, H13CP, DCP, and D13CP have been measured in the millimeter-wave and submillimeter-wave ranges. For HCP and DCP, the rotational spectra in the vibrationally excited statesv2= 1, 2 andv3= 1 have also been analyzed. The equilibrium structure has been calculatedab initioand experimentally redetermined. The derived structure is compared to those of the similar molecules FCP and ClCP and its accuracy is discussed. The equilibrium structure of FCP has also been redetermined by combining the experimental rotational constants andab initiocalculations.
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