Abstract

The first ( Z (1)) and second ( Z (2)) approximations to the rotational number of the Ar—N 2 system are compared for a range of temperatures. Although Z (1) and Z (2) differ by a significant amount their difference remains nearly constant as a function of temperature. The effects of mass and potential parameter variations on the rotational relaxation time are also studied. When the mass of the incoming atom is decreased Z (2) goes through a minimum while Z (1) steadily increases.

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