Abstract
Abstract The intensity anomalies observed in the 12-12 ( N = 10), 14-14 ( N = 7, 10), and 17-14 ( N = 17, 19) lines of the CN violet bands are found to be due to rotational perturbations by the CN ( 4 Π) state. Experimental evidence that the perturbing state is 4 Π, predicted theoretically by Schaefer and Heil, is presented, and the spectroscopic constants of this state are estimated.
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