Rotational diffusion of carbon monoxide in various simple liquids

Abstract

Infra-red spectra of CO dissolved in liquid N2, O2, Ar, Xe and CH4 have been recorded both in the fundamental and the first overtone. From the band profiles, rotational correlation functions, band moments and intermolecular mean-square torques have been calculated. With the help of Gordon's rotational diffusion model [1] we computed the theoretical correlation functions in the ‘M-diffusion’ (including or not a distribution of angular momentum correlation times) and ‘J-diffusion’ limits. The validity of the Gordon and Debye diffusion models in the various dense gases is discussed.