Abstract
Rotational assignment of the high-resolution fluorescence excitation spectrum of the 14NO3 radical in the B∼2E′←X∼2A2′ transition 0–0 band region located around 15,100cm−1 was made with the help of the ground state combination differences and the observation of Zeeman effect. We successfully identified several rotational line series based on the newly obtained rotational assignments of 162 lines with |k″|⩽15 and J′⩽18.5 quantum numbers, and we estimated the effective molecular constants of the excited vibronic states.
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