Abstract

Although platinum and platinum group metals (PGMs) catalysts are the most efficient for oxygen reduction reaction, the cost and scarcity of the metals are the reason to look for alternative electrocatalysts. Transition metals, such as cobalt, iron, and nickel, have shown promise as an alternative catalyst to oxygen reduction reactions (ORR). In this work, we electrochemically synthesized nickel-cobalt-iron trimetallic alloy nanoparticles dispersed on carbon Vulcan using Rotating Disk Slurry Electrodeposition (RoDSE). This technique is an energy-efficient green method to synthesize well-dispersed catalysts on carbon and oxide supports for various applications including the oxygen reduction reaction (ORR) for fuel cell applications. Cobalt-nickel iron nanoparticles have been well dispersed in 20 mg carbon Vulcan XC-72R using a negative potential (-1.05V vs Ag/AgCl-sat KCl) in a saturated Argon environment. The electrodeposition potential was obtained from cyclic voltammetry analysis of the metal salts in 0.1m KClO4 solution with an electrochemically cleaned glassy carbon electrode. The starting material precursors were iron chloride, nickel acetate, and cobalt acetate in 0.1 M KClO4 aqueous solution. A 500 micromolar metal salt solution aliquot was added for the electrodeposition every 20 minutes, with a total of 12 aliquots.Compared with commercially available 20% Pt/Vulcan, the synthesized catalyst shows comparable mass activity and durability with an onset potential of 0.78V vs RHE(@0.01mA/cm2), limiting current density of 5.56mA/cm2 and half wave potential of 0.66V vs RHE.The X-ray diffraction (XRD) studies and transmission electron microscopy showed that trimetallic nanoparticles are formed and deposited on the carbon Vulcan support. Moreover, scanning electron microscopy, X-ray fluorescence studies, and transmission emission microscopy show the presence of trimetallic nanoparticles. The RDE and RRDE studies show that the synthesized material is active and may lead to a good and inexpensive catalyst for ORR.

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