Rotating disk electrode study of borohydride oxidation in a molten eutectic electrolyte and advancements in the intermediate temperature borohydride battery

Abstract

Abstract The electrode kinetics of the NaBH 4 oxidation reaction (BOR) in a molten NaOH-KOH eutectic mixture is investigated by rotating disk electrode (RDE) voltammetry on electrochemically oxidized Ni at temperatures between 458 K and 503 K. The BH 4 − diffusion coefficient in the molten alkali eutectic together with the BOR activation energy, exchange current density, transfer coefficient and number of electrons exchanged, are determined. Electrochemically oxidized Ni shows excellent BOR electrocatalytic activity with a maximum of seven electrons exchanged and a transfer coefficient up to one. X-ray photoelectron spectroscopy (XPS) reveals the formation of NiO as the catalytically active species. The high faradaic efficiency and BOR rate on oxidized Ni anode in the molten electrolyte compared to aqueous alkaline electrolytes is advantageous for power sources. A novel molten electrolyte battery design is investigated using dissolved NaBH 4 at the anode and immobilized KIO 4 at the cathode. This battery produces a stable open-circuit cell potential of 1.04 V, and a peak power density of 130 mW cm −2 corresponding to a superficial current density of 160 mA cm −2 at 458 K. With further improvements and scale-up borohydride molten electrolyte batteries and fuel cells could be integrated with thermal energy storage systems.