Rosin-based chiral wormlike Micelles: Rheological behavior and its application in preparing ultrasmall gold nanoparticles

Abstract

Innovations in surfactant structures are a feasible way to prepare unique molecular aggregates with interesting properties. Herein, taking dehydroabietic acid as the starting material, a new amine oxide surfactant, abbreviated as R-8-AO, was synthesized. Cryogenic transmission electron microscopy (cryo-TEM) images and circular dichroism (CD) spectra reveal that at suitable concentrations, R-8-AO molecules form rarely discovered right-handed chiral wormlike micelles, which have a cross-sectional diameter of 5–6 nm. The overlap concentration of R-8-AO is approximately 8 mM, above which the wormlike micelles began to entangle in solutions. Due to the strong van der Waals forces between R-8-AO molecules, the scaling law gives an exponent of 7.88, which is higher than the theory predicted value. Gold nanoparticles were synthesized in-situ by irradiating mixed solutions of HAuCl4 and wormlike micelles formed by R-8-AO with UV light. These ultrasmall spherical gold nanoparticles, which are located at the surface of wormlike micelles, have a uniform particle size of 3 ± 1 nm, as observed by TEM. In addition, the gold nanoparticles form a worm-like morphology induced by the wormlike micelles, showing soft-aggregate-directed nanoparticle assembly. This work is first to reveal the effectiveness of preparing ultrasmall gold nanoparticles with new morphological wormlike micelles as soft templates. The resulting organic-inorganic hybrid aggregates are also expected to find applications in catalysis and electronic fields.