Room-Temperature Smart Sensor Based on Indium Acetate-Functionalized Perovskite CsPbBr3 Nanocrystals for Monitoring Electrolyte in Lithium-Ion Batteries.

Abstract

Monitoring electrolyte components is an effective means of determining the safety status of lithium-ion batteries. In this study, indium acetate was taken as a ligand to functionalize perovskite CsPbBr3 nanocrystals, and then the room-temperature electrolyte sensor based on CsPbBr3 nanocrystals with ligand indium acetate was prepared. The sensor offers high response, long-term stability (21 days), and low detection limits for ethyl methyl carbonate (10 ppm), diethyl carbonate (10 ppm), and ethyl butyrate (1 ppm) gases at room temperature and boasts a fast response/recovery time (1500 ppm, 58.27/103.82 s, 33.58/40.62 s, and 45.05/103.08 s, respectively). Density functional theory results show that the gas sensitivity comes from the adsorption of an electrolyte, which changes the density-of-state distribution so that the electrical response curve changes. And using computational fluid dynamics simulation, it was found that the time required for gas detection by the built-in sensor (3.1 s) was 8.7 times shorter than that of the implantable sensor. This work provides inspiration and rationale for embedding and integrating room-temperature sensors into lithium-ion batteries to monitor safety and health conditions.