Room temperature Self-healable and extremely stretchable elastomer with improved mechanical Properties: Exploring a simplistic Metal-Ligand interaction

Abstract

The dynamic supramolecular crosslinking reactions like imine bond formation, disulfide metathesis reactions, Diels Alder reactions, metal–ligand interactions, H-bonding, and ionic interactions are broadly used for the self-healing application of elastomers. Herein, we have developed a new self-healable and extremely stretchable elastomer based on robustness and dynamic metal–ligand coordination bonds between the API ligand and the Zn2+ metal ion moieties incorporated onto the XNBR rubber backbone. The FT-IR analysis confirmed the formation of amide linkage and metal–ligand coordination bonds into the XNBR rubber backbone. The healing performance and mechanical properties of various rubber compounds depend on the dosages of metal ions and the type of crosslinking systems. The metal–ligand crosslink compounds exhibit excellent healing performance over the sulfur crosslinking system. Differential scanning calorimetry, rubber process analyzer, crosslinking density, and morphology studies are indicated to characterize the metal–ligand interactions in the XNBR rubber matrix. The metal–ligand cross-linked XNBR rubber with 3 parts of Zn2+ metal ion demonstrates an excellent healing performance of 91.2%, with the tensile strength of 5.7 ± 0.8 MPa at room temperature for 24 h is much higher than the covalently cross-linked elastomers. The metal–ligand coordination bonds are entirely dynamic and thermoreversible during the rebuilding process and obtain an excellent self-healing property than the sulfur curing system.