Room-Temperature Self-Healable Blends of Waterborne Polyurethanes with 2-Hydroxyethyl Methacrylate-Based Polymers.

Abstract

The design of self-healing agents is a topic of important scientific interest for the development of high-performance materials for coating applications. Herein, two series of copolymers of 2-hydroxyethyl methacrylate (HEMA) with either the hydrophilic N,N-dimethylacrylamide (DMAM) or the epoxy group-bearing hydrophobic glycidyl methacrylate were synthesized and studied as potential self-healing agents of waterborne polyurethanes (WPU). The molar percentage of DMAM or GMA units in the P(HEMA-co-DMAMy) and P(HEMA-co-GMAy) copolymers varies from 0% up to 80%. WPU/polymer composites with a 10% w/w or 20% w/w copolymer content were prepared with the facile method of solution mixing. Thanks to the presence of P(HEMA-co-DMAMy) copolymers, WPU/P(HEMA-co-DMAMy) composite films exhibited surface hydrophilicity (water contact angle studies), and tendency for water uptake (water sorption kinetics studies). In contrast, the surfaces of the WPU/P(HEMA-co-GMAy) composites were less hydrophilic compared with the WPU/P(HEMA-co-DMAMy) ones. The room-temperature, water-mediated self-healing ability of these composites was investigated through addition of water drops on the damaged area. Both copolymer series exhibited healing abilities, with the hydrophilic P(HEMA-co-DMAMy) copolymers being more promising. This green healing procedure, in combination with the simple film fabrication process and simple healing triggering, makes these materials attractive for practical applications.