Abstract
We report an observation of room temperature ferromagnetism in Ge nanowires doped with Mn. High-density arrays of ${\mathrm{Ge}}_{1\ensuremath{-}x}{\mathrm{Mn}}_{x}\phantom{\rule{0.2em}{0ex}}(x=1%--5%)$ nanowires with the smallest diameter of 35 nm have been synthesized within the pores of anodized aluminium oxide membranes using a supercritical fluid inclusion-phase technique. Structural analysis of the nanowires proved the existence of a highly crystalline germanium host lattice containing discrete manganese atoms. All of the nanowires studied displayed ferromagnetic properties at room temperature. Ferromagnetic ordering reaches a maximum at intermediate Mn concentrations. The magnetic properties of the nanowires can be understood by considering the influence of co-dopant nonmagnetic impurities and nanowire/membrane interfaces.
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