Role of structural characteristics of MoS2 nanosheets on Pb2＋ removal in aqueous solution

Abstract

In this study, ultrasonic-assisted liquid-phase stripping and hydrothermal synthesis were used to prepare the two structural types of MoS2 nanosheets, namely u-MoS2 and h-MoS2, respectively. The u-MoS2 and h-MoS2 were characterized by various techniques, and the profound relationship between the structure and preparation method was also identified. Results indicated that adsorptions of Pb2＋ onto both u-MoS2 and h-MoS2 nanosheets reached equilibrium after 30 min at higher rates. The removal efficiencies of Pb2＋ by h-MoS2 and u-MoS2 nanosheets were 98.4% and 20.6% under the condition of low dosage (60 mg/L). The Pb2＋ by h-MoS2 adsorption fitted well to the Langmuir adsorption isotherm with the adsorption capacity of 174.0 mg/g while the Pb2＋ adsorption by u-MoS2 fitted well to the Freundlich isotherm (n=1). The obvious discrepancy suggested that the adsorption performance was directly associated with their structural properties, which were induced by two different synthesis methods. Based on these results, the effects of operational parameters (pH, dosage and existing ions) on Pb2＋ adsorption using h-MoS2 were further investigated. The dosage greatly affected the adsorption capacity and removal efficiency, while pH and coexisting ions had small effects on adsorption performance. In short, this study could help to better understand the role of MoS2 nanosheets’ structures obtained by different preparation methods for adsorption of heavy metal ions in aqueous solution.