Abstract
By using gaseous oxygen-18, the oxidation of propylene on a bismuth molybdate catalyst has been shown to include sorbed oxygen at low catalyst temperatures and predominantly oxygen from the lattice at higher temperatures at which oxygen-ion mobility in the lattice becomes appreciable. The oxygen atoms of oxygen-18-enriched carbon dioxide exchanged very rapidly with lattice oxygen and participated in oxidation of propylene to labeled acrolein. In the heterogeneous oxidation of allyl alcohol, the original oxygen in allyl alcohol is found in the acrolein product.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
