Role of Reaction Time on the Electrical Conductivity, Thermal Stability and Photoluminescence Property of Polyanilne Nanofibers

Abstract

AbstractDirect evidence of the control of yield, thermal stability and photoluminescence property of the polyaniline (PANI) nanofibers have been reported by systematically varying the reaction time in the range of 2–6 hours (h) in the synthesis process. Both FTIR and UV–visible spectra revealed the formation of PANI fibers for all synthesis batches. The mass of the obtained PANI was increased with the increase of reaction time from 2 to 6 h. FESEM data confirmed the formation of PANI in nanofibers form for all the synthesis batches. TGA data showed that the highest thermal stability of PANI nanofibers could be obtained for the 4 h reaction time. PL data indeed showed the variation of luminescence intensity of PANI with the reaction time which indicate the formation of different quality fibers in terms of theirπconjugation. Thus the three main results can be summarized: one is the increase of PANI fibers yield and another two are the thermal stability and luminescence property modification which shows that such properties of PANI can be controlled by varying the reaction time of the synthesis process.