Role of oxidation catalysis in after-treatment of exhaust gases of diesel engines

Abstract

Introduction (problem statement and relevance). The oxidation catalysis provides the necessary efficiency and performance of diesel filters for trapping dispersed particles and systems for selective treatment of nitrogen oxides. In addition, oxidation catalysts can be a tool for neutralizing emissions of methane and some non-regulated but very hazardous polycyclic and partially oxidized hydrocarbons. There are also poorly studied theoretical issues of oxidation catalysis associated with mutual influence of toxic components contained in exhaust gases of diesel engines.The purpose of the study is to clarify the oxidation catalysis role in the general problem of after-treatment of toxic emissions of diesel engines, development and testing of catalysts and converters for neutralization of toxic combustion products of engines powered by natural gas.Methodology and research methods. Research into the catalysts under flow conditions using modern methods of gas analysis, IR spectroscopy, engine tests of the developed catalytic converters.Scientific novelty and results. The paper shows the role of oxidation catalysis in solving the common problems of after-treatment of hazardous emissions of diesel engines including both direct after-treatment of toxic compounds and supporting functions. Catalysts of higher efficiency and a series of converters for gas engines have been developed. Innovative methods to increase the resistance of oxidation catalysts to sulfur oxides have been proposed.Practical significance. The developed catalysts and converter designs are recommended for implementation in KAMAZ-820.52-260 and Cummins 250 and 280 gas engines.