Role of NiO Nanoparticles in Enhancing Structure Properties of TiO2 and Its Applications in Photodegradation and Hydrogen Evolution.

Abstract

Pure and modified mesoporous TiO2 nanoparticles with different loadings of NiO (3–20.0 wt %) were prepared through the surfactant-assisted sol–gel approach with the use of cetyltrimethylammonium bromide as a template. The optical and structural properties of different samples were examined using N2 adsorption–desorption analysis, energy-dispersive spectroscopy, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, UV–vis spectroscopy, Fourier transform infrared spectroscopy, and photoluminescence (PL) spectroscopy. X-ray diffraction results confirmed the insertion of Ni2+ into the lattice of TiO2, and the crystallite size reduced remarkably after the addition of NiO. The diffuse reflectance spectroscopy spectra displayed obvious red shift in the absorption edges, and new absorption bands appeared in the visible region when NiO was added, which indicates the formation of surface defects and oxygen vacancies. The optical band gap of TiO2 reduced sharply when the contents of NiO were increased. The increase in the surface defects as well as oxygen vacancies were examined using PL spectroscopy. The photocatalytic performance of the as-synthesized samples was investigated over photodegradation of brilliant green (BG) and phenol and hydrogen generation under visible light. 10% NiO/TiO2 exhibited the highest photocatalytic efficiency. The photocatalytic activity was improved due to the creation of a p–n junction at the interface of NiO/TiO2, which efficiently promotes the separation of photogenerated electron/hole pairs and consequently enhances its photodegradation activity. According to the photocatalytic activity results, NiO contents were considered one of the most important factors affecting the photodegradation of BG and phenol and H2 evolution. Also, we discussed the mechanism of photodegradation, mineralization (total organic carbon), and photocatalytic reaction kinetics of BG and phenol.