Abstract

ZnF2–P2O5–TeO2 glasses containing different concentrations of MnO (ranging from 0 to 0.6%) were prepared. A number of studies, viz. differential thermal analysis, optical absorption, thermo luminescence, infrared spectra, magnetic susceptibility, elastic properties (Young's modulus Y, shear modulus n and micro hardness H) and dielectric properties (constant ε, loss tanδ, a.c. conductivity σac over a range of frequency and temperature and dielectric breakdown strength), of these glasses were carried out as a function of manganese ion concentration. The analysis of the results indicate manganese ions mostly exist in Mn2+ state in these glasses when the concentration of MnO≤0.4% and above this concentration manganese ions predominantly exist in Mn3+ state; from this analysis an attempt is made to identify the role of these ions on the stability of glass network.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.