Abstract
In this study, the role of lanthanide elements (Ce, Gd, La, and Yb) on Pd/TiO 2 catalysts in the catalytic reduction of NO with methane was investigated. Steady-state reaction experiments in the presence of oxygen showed that the addition of lanthanide elements increases the oxygen resistance of the catalyst. The post-reaction XPS characterization results revealed that majority of the Pd sites remained in the zero oxidation state in the presence of Ce or Gd. The effect of SO 2 (145 ppm) and H 2O (0–6.6%) in NO–CH 4–O 2 reaction over supported Pd and Gd–Pd catalysts was also investigated. Over the Gd–Pd catalyst with the presence of SO 2, more than 70% NO conversion was obtained for over 6 h while the Pd only catalyst showed a sharper drop in NO conversion. Over the Gd–Pd catalyst, the presence of H 2O showed no effect on NO conversion activity (>99% conversion) during the 18 h the catalyst was kept on stream. Among the lanthanide elements tested, Gd is the most effective, allowing the use of above stoichiometric oxygen concentration.
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