Abstract
The analysis of the crystal structures of two new mononuclear Pd(II) compounds, containing 3,5-disubstituted-2-(2′-pyridyl)pyrrole ligands, reveals that the use of fluoroaliphatic (1) versus aliphatic (2) substituting groups on the HLn ligand induces substantial changes in their supramolecular architectures. Despite the common molecular geometry suitable for the formation of mixed “aryl embraces”, “tetris-like” columnar heterochiral (1) and helicoidal chiral (2) organizations are formed. The resulting supramolecular packing affects their solid state photophysical properties.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
