Role of Elementary Reactions on Flame Structure and Unsteady Behavior of Two-Dimensional Fuel Jet Diffusion Flame.

Abstract

A direct numerical simulation of two-dimensional fuel jet flames developed in a co-flowing air stream was made considering rather complex finite chemistry in order to clarify the role of elementary reactions on flame structure and its unsteady behavior. The governing equations were discretized and numerically integrated by using a finite volume method. The temperature dependence of thermodynamical properties was taken into account and the transport properties were calculated according to the simplified transport model proposed by Smooke et al. Chemical reactions were described by the Smooke's skeletal methane-air reaction mechanism. It was found that large-scale fluctuations were produced in the downstream where a decrease in temperature occurred at some instants leading to local extinction. Comparing with the results of counterflow laminar diffusion flame, it was also found that the hypothesis of laminar flamelet model can be accepted even for the case of the unsteady jet flame with the local extinction. Furthermore, a better understanding of extinction mechanism was obtained : In the turbulent region of the flame, fuel is converted by the large-scale vortices into the reaction zone at high supply rates inducing CH3, CH3O, CH2O and HCO production. At some instant, the increase of mixing rates will results in a decrease of temperature causing the consumption of available active radicals due to the activity of some exothermic reactions, and the slow-down of the reactions producing new OH, O, H radicals. The radical pool is no longer available for chain reactions to proceed, resulting in an extinction.