Abstract
Achieving fast charging in all-solid-state lithium metal batteries is a critical challenge. In this regard, the composition and spatial arrangement of constituent phases (e.g., active material, binder, conductive diluent, solid electrolyte) in the porous cathode play a major role in determining the ionic/electronic percolation pathways and internal resistances. The underlying heterogeneity in the cathode microstructure can result in non-uniform kinetic-transport processes, and thereby necessitates a detailed understanding of its influence on the electrochemical performance. In this study, the mesoscale underpinnings of the cathode microstructural heterogeneity will be examined in the context of fast charge extremes for all-solid-state lithium metal batteries.
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