Role of C–H···Au and Aurophilic Supramolecular Interactions in Gold–Thione Complexes

Abstract

The role of noncovalent gold–hydrogen and aurophilic interactions in the formation of extended molecular systems of gold complexes was studied. Three new gold compounds with a heterocyclic thione ligand N-methylbenzothiazole-2-thione (mbtt), namely, [AuCl(mbtt)] (1), [AuBr(mbtt)] (2), and [Au(mbtt)2][AuI2]1–n[I3]n (3), were synthesized and characterized. The halide ligand had a considerable effect on the complex structures and thus to noncovalent contacts. Intermolecular C–H···Au and aurophilic Au···Au contacts were the dominant noncovalent interactions in structures 1–3 determining the supramolecular arrays of the gold complexes. In 1 and 2, unusual intermolecular C–H···Au gold–hydrogen contacts linked the adjacent mononuclear molecules to a chain structure, while in 3 the change in the ligand coordination induced the formation of an intermolecular aurophilic interaction. Au···I, π–π, halogen–halogen, and hydrogen bonding interactions supported further the supramolecular array of 3. The interactions were...