Abstract
Functionalized perfluoroalkyl lithium β-diketonates LiL react with terbium (III) salts in methanol to give heterobimetallic complexes of general formula [(TbL3)(LiL)(MeOH)]. The length of both fluoroalkyl and hydrocarbon substituents in ligand was found to affect the crystal packing of metal complexes. Photoluminescence of heterobimetallic β-diketonates in the solid state is reported.
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