Robust surface light scattering spectroscopy for fluid interfaces

Abstract

Surface Light Scattering Spectroscopy (SLSS) can characterize the dynamics of an interface between two immiscible fluids by measuring the frequency spectrum of coherent light scattered from thermophysical fluctuations—‘ripplons’. In principle, and for many interfaces, SLSS can simultaneously measure surface tension and viscosity, with the potential for higher-order properties, such as surface elasticity and bending moments. Previously, this has been challenging. We describe and present some measurements from an instrument with improvements in optical design, specimen access, vibrational stability, signal-to-noise ratio, electronics, and data processing. Quantitative improvements include total internal reflection at the interface to enhance the typically available signal by a factor of order 40 and optical improvements that minimize adverse effects of sloshing induced by external vibrations. Information retrieval is based on a comprehensive surface response function, an instrument function, which compensates for real geometrical and optical limitations, and processing of almost real-time data to report results and their likely accuracy. Detailed models may be fit to the power spectrum in real time. The raw one-dimensional digitized data stream is archived to allow post-experiment processing. This paper reports a system design and implementation that offers substantial improvements in accuracy, simplicity, ease of use, and cost. The presented data are for systems in regions of low viscosity where the ripplons are underdamped, but the hardware described is more widely applicable.