Abstract
The ionization energies of some chromium and tungsten pentacarbonyl complexes of the type [M(CO)5] xL (L = N2H2, N2H4, NH3; x = 1 or 2 for N2H4 or x = 1 for N2H2) are reported. The results are discussed in terms of the effects of σ-donor and π-acceptor bonds on XPS data. Satellite lines, which can be explained in terms of a shake-up process, give information about the nature of the metal-ligand bond. These shake-up processes are, to a large extent, specific to the atoms of the acceptor groups. The spectroscopic and chemical importance of multi-peak structures of XPS bands is emphasised
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