RKR-потенциалы молекул -=SUP=-14-=/SUP=-N-=SUP=-16-=/SUP=-O, -=SUP=-16-=/SUP=-OH в основном электронном состоянии

Abstract

In this work, molecular parameters of the Dunham type, obtained from the global processing of the experimental vibrational-rotational and rotational transition frequencies of ^{14}N^{16}O and ^{16}OH molecules, were used to construct the RKR potential energy curves. Pointwise defined potentials were approximated by the expansions in variable z_{S}=(r-r_{e})/r. Ab initio calculations of the potential energy functions of these molecules were carried out using the MOLPRO program. Comparisons of the obtained results with those known from the literature are given.