Abstract

In this work, molecular parameters of the Dunham type, obtained from the global processing of the experimental vibrational-rotational and rotational transition frequencies of ^{14}N^{16}O and ^{16}OH molecules, were used to construct the RKR potential energy curves. Pointwise defined potentials were approximated by the expansions in variable z_{S}=(r-r_{e})/r. Ab initio calculations of the potential energy functions of these molecules were carried out using the MOLPRO program. Comparisons of the obtained results with those known from the literature are given.

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