Abstract

Lithium-ion Batteries (LIB) are an essential facilitator of the decarbonisation of the transport and energy system, and their high energy densities represent a major technological achievement and resource for humankind. In this research, it has been argued that LIBs have penetrated everyday life faster than our understanding of the risks and challenges associated with them. The current safety standards in the car industry have benefited from over 130 years of evolution and refinement, and Electric Vehicle (EV) and LIB are comparably in their infancy. This paper considers some of the issues of safety over the life cycle of batteries, including: the End of Life disposal of batteries, their potential reuse in a second-life application (e.g. in Battery Energy Storage Systems), recycling and unscheduled End of Life (i.e. accidents). The failure mechanism and reports from a range of global case studies, scenarios and incidents are described to infer potential safety issues and highlight lessons that can be learned. Therefore, the safety risks of LIBs were categorised, and the regularity requirements to create and inform a wider debate on the general safety of LIBs were discussed. From the analysis, a range of gaps in current approaches have been identified and the risk management systems was discussed. Ultimately, it is concluded that robust educational and legal processes are needed to understand and manage the risks for first responders and the public at large to ensure a safe and beneficial transition to low carbon transportation and energy system.

Highlights

  • Lithium-ion batteries (LIBs) have penetrated deeply into society, finding a wide range of applications in personal electronic devices since their discovery and development in the 1980s and 90s, and more recently in larger energy systems for traction and energy storage

  • Among the different life cycle stages of LIBs, the focus of this review is on the End of Life (EoL) of LIBs, including repurposing (i.e. second life application in Battery Energy Storage Systems (BESS)) and recycling of LIBs (Fig. 1) among the process stages

  • For a balanced consideration of any safety concerns around LIBs, it is imperative that these hazards be situated against a broader landscape of the dangers that arise from pursuing our present fossil fuel trajectory

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Summary

Introduction

Lithium-ion batteries (LIBs) have penetrated deeply into society, finding a wide range of applications in personal electronic devices since their discovery and development in the 1980s and 90s, and more recently in larger energy systems for traction and energy storage. This is mainly owing to the unique characteristics of LIB technology, i.e. high energy densities, high voltage, good stability, low self-discharge rate, long-life cycle and availability of a wide range of chemistries with diverse electrode designs [1,2]. Open Circuit Voltage (OCV) The potential difference (voltage) across the terminals of a cell or battery when no current is allowed to flow This can be correlated with the State of Charge (SoC). There have been many exam­ ples of second-use LIBs being used in stationary Battery Energy Storage Systems (BESS), for example in the Johan Cruijff Arena in Amsterdam [18]

Why focusing on LIB risk management and safety issues?
Contextualising the relative levels of risk of electric vehicle LIBs
Performance considerations of second-life batteries
The effect of an unregulated market for used EV batteries
Potential failure mechanisms of LIBs
Origins and categorisation of risks associated with LIBs
Fire risks
Risks to the natural environment
End of Life LIB incidents
LIB incidents in BESS
LIB incidents in waste treatment facilities
Risk management systems to ensure LIB safety
Regulatory regimes and information gaps
Discussions and suggestion for best practices
Findings
Conclusions
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