Abstract
Abstract The N-silylphosphoranimines, Me3SiN═PR2X, undergo a variety of useful reactions such as condensation polymerization, Si-N bond cleavage, nucleophilic substitution at phosphorus, and deprotonation of pendent P-methyl groups. Several ring systems, including cyclic phosphazenes and novel B-N/P-N hybrid derivatives, are accessible from these Si-N-P reagents.
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