Abstract
The ground state ring puckering splitting of the cyclopentane ring of indan has been precisely determined (ΔE01=22.364(1) MHz) by measuring the very weak μc-type transitions with pulse jet Fourier transform microwave spectroscopy. In addition, the rotational spectra of all 13C monosubstituted isotopologues have been assigned and measured in natural abundance, leading to an accurate structure of the heavy atoms frame.
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