Abstract
AbstractTris(imino)thietanes (1a‐c) manifest a dual reactivity in ring‐opening reactions. Methanol, diethylamine and ethanethiol all attack the thietane ring at the electrophilic C4‐atom to yield open‐chain products of type 2‐4. On the other hand, the reactions of 1a‐c with hydrazoic acid occur with cleavage of the C2‐S bond producing tetrazoles of type 6. Sodium azide and 1a reacted to furnish the unexpected product 9. Product characterization was based on spectral (IR, 1H NMR, 13C NMR, mass spectra) and analytical properties, and also, in the cases of 6b and 9, on an X‐ray diffraction analysis.
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