Abstract
Abstract1‐Ethylbicyclo[2.2.1]hept‐2‐ene has been polymerized using a range of metathesis catalysts and the structure of the polymers determined by 13C n.m.r. spectroscopy. For a given catalyst the cis double bond content was lower and the head‐tail bias greater than for polymers of the 1‐methyl analogue. This is interpreted in terms of enhanced steric and polar effects brought about by the ethyl substituent.
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