Abstract
For the mechanistic explanation of the Fischer‐Tropsch synthesis, model reactions at dimetallacyclopropane complexes such as 1 are of considerable interest. Base‐induced, ring‐opening has now been achieved for the first time. In this way, methylene bridges react with coordinated CO to afford the salt 2, which was isolated and fully characterized. equation image
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More From: Angewandte Chemie International Edition in English
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