Abstract
The possibility of opening cyclic iminoethers and forming linear polymers or copolymers under the action of charge transfer complexes has been studied. The polymerization of 2-methyl-2-oxazoline, acting as donor, proceeds in the presence of various organic electron-acceptors such as tetracyanoethylene 7,7,8,8-tetracyanoquinodimethane and 2,4,7-trinitrofluorenone. Initiation takes place by charge transfer complexes formed between the monomer and the acceptor. With acceptors which possess polymerizable bonds, i.e. tetracyanoethylene and tetracyanoquinodimethane, copolymers are obtained.
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