Abstract
Ring-opening isomerization polymerization was developed using a combination of a ring-opening reaction of epoxides and subsequent Brook rearrangement. An epoxy monomer with a benzyltrimethylsilyl group was designed for the polymerization. Characterization of the obtained polymer by NMR and MALDI-TOF-MS indicated that polymerization proceeded exclusively via a ring-opening-isomerization anionic polymerization mechanism.
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Schedule a callMore From: Journal of the Chemical Society Chemical Communications
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