Abstract
Di[1,2,3]triazolo[1,5- a :5’,1’- d ][3,1,5]benzothiadiazepine treated with butyllithium undergoes ring opening via the thiophilic addition of butyllithium at the C–S bond, whereas 9,10-dihydrodi[1,2,3]triazolo[1,5- b :5’,1’- f ][1,3,6]thiadiazepine mainly undergoes lithiation of the methylene group followed by C–N bond cleavage to give 1-vinyltriazolyl sulfide.
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