Abstract

Big spin! In the presence of 2-aminopropane-1,2-diol, the reaction of 1,1,1-tris-(hydroxylmethyl)propane and [Mn(acac)2] in MeCN yielded a novel ring-like octadecanuclear mixed-valence manganese cluster complex, which exhibits an overall ferromagnetic property and possesses a large spin ground state of 20.

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