Abstract
Access to novel imine-substituted 1,2-azaborinines, as well as highly arylated boracyclohexa-3,5-dienes has been developed by ring expansion of boroles with diazoalkanes with varying degrees of steric bulk. The formation of a diazoalkane intermediate is also discussed for the reaction of ortho-brominated p-tolyl-azide with 1,2,3,4,5-pentaphenylborole. Structural details as well as UV/Vis spectroscopic and cyclic voltammetric data are provided. These boron-containing heterocycles have the potential to serve as building blocks for boron-containing materials.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Paper version not known
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
