Rigorous description of an energy spectrum of the isopropanol molecule taking into account the internal rotation of methyl tops

Abstract

By using the group chain methods, a rigorous algebraic model is constructed to describe the energy spectrum of the isopropanol molecule (CH3)2CHOH with an allowance for the internal motion of hydroxil and two identical methyl tops. The model is rigorous in the sense that its correctness is limited only by the correctness of a symmetry chosen to describe internal dynamics of the molecule.