Ribbon phase in a phase-separated lyotropic lamellar-sponge mixture under shear flow.

Abstract

We report the effect of shear flow on a phase-separated system composed of lyotropic lamellar (L(alpha)) and sponge (L3) phases in a mixture of brine, surfactant, and cosurfactant. Optical microscopy, small-angle light, and x-ray scattering measurements are consistent with the existence of a steady state made of multilamellar ribbon-like structures aligned in the flow direction. At high shear rates, these ribbon-like structures become unstable and break up into monodisperse droplets resulting in a shear-thickening transition.